Self-organization of star-shaped columnar liquid crystals with a coaxial nanophase segregation revealed by a combined experimental and simulation approach

Beltrán, Eduardo and Garzoni, Matteo and Feringán, Beatriz and Vancheri, Alberto and Barberá, Joaquín and Serrano, José Luis and Pavan, Giovanni Maria and Giménez, Raquel and Sierra, Teresa (2015) Self-organization of star-shaped columnar liquid crystals with a coaxial nanophase segregation revealed by a combined experimental and simulation approach. Chemical Communications, 51 (10). pp. 1811-1814. ISSN 1359-7345

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Abstract

Fully consistent X-ray data and molecular dynamics simulations on new star-shaped liquid crystals yield two nanosegregated architectures with a coaxial stacking of two functional discotic units: tris(triazolyl)triazine and triphenylene. Analysis of lattice order along the principal axes reveals preferential staggered arrangement of the stacked molecules in the columnar assembly.

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